Photochemical decoration of silver nanoparticles on graphene oxide nanosheets and their optical characterization

http://repository.vnu.edu.vn/handle/VNU_123/29630

Nanohybrid materials based on silver nanoparticles (Ag-NPs) and graphene oxide (GO) are attracting considerable research interest because of their potential many applications including surface-enhanced Raman scattering, catalysis, sensors, biomedicine and antimicrobials.


In this study, we established a simple and effective method of preparing a finely dispersed Ag-GO aqueous solution using modified Hummer and photochemical technique.
The Ag-NPs formation on GO nanosheets was analyzed by X-ray diffraction, transmission electron microscopy, Raman spectroscopy, and Fourier-transform infrared spectroscopy.
The average size of Ag-NPs on the GO nanosheets was approximately 6-7 nm with nearly uniform size distribution.
The Ag-GO nanohybrid also exhibits an adsorption band at 435 nm because of the presence of Ag-NPs on the GO nanosheets.
Photoluminescence emission of the Ag-GO nanohybrid was found at 400 and 530 nm, which can be attributed to the interaction between the luminescence of exploited GO nanosheets and localized surface plasmon resonance from metallic Ag-NPs.
The observed excellent optical properties of the as-prepared Ag-GO nanohybrid showed a significant potential for optoelectronics applications

Title: Photochemical decoration of silver nanoparticles on graphene oxide nanosheets and their optical characterization
Authors: Lan, Nguyen Thi
Chi, Do Thi
Dinh, Ngo Xuan
Keywords: Ag-GO nanohybrid
Green synthesis
Optical properties
Issue Date: 2014
Publisher: Journal of Alloys and Compounds
Citation: Scopus
Abstract: Nanohybrid materials based on silver nanoparticles (Ag-NPs) and graphene oxide (GO) are attracting considerable research interest because of their potential many applications including surface-enhanced Raman scattering, catalysis, sensors, biomedicine and antimicrobials. In this study, we established a simple and effective method of preparing a finely dispersed Ag-GO aqueous solution using modified Hummer and photochemical technique. The Ag-NPs formation on GO nanosheets was analyzed by X-ray diffraction, transmission electron microscopy, Raman spectroscopy, and Fourier-transform infrared spectroscopy. The average size of Ag-NPs on the GO nanosheets was approximately 6-7 nm with nearly uniform size distribution. The Ag-GO nanohybrid also exhibits an adsorption band at 435 nm because of the presence of Ag-NPs on the GO nanosheets. Photoluminescence emission of the Ag-GO nanohybrid was found at 400 and 530 nm, which can be attributed to the interaction between the luminescence of exploited GO nanosheets and localized surface plasmon resonance from metallic Ag-NPs. The observed excellent optical properties of the as-prepared Ag-GO nanohybrid showed a significant potential for optoelectronics applications
Description: Journal of Alloys and Compounds Volume 615, 5 December 2014, Pages 843-848
Journal of Alloys and Compounds
URI: http://repository.vnu.edu.vn/handle/VNU_123/29630
ISSN: 09258388
Appears in Collections:Bài báo của ĐHQGHN trong Scopus



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